Description
Product Name: Indium trichlorideCas No.: 12672-70-7
MF: Cl3In
MW: 221.18
Description: Indium(III) chloride is the chemical compound with the formula InCl3. This colorless salt finds some use in organic synthesis as a Lewis acid. It is also the most available soluble derivative of indium.
Being a relatively electropositive metal, indium reacts quickly with chlorine to give the trichloride. Indium trichloride is very soluble and deliquescent. A synthesis has been reported using an electrochemical cell in a mixed methanol-benzene solution.
Like AlCl3 and TlCl3, InCl3 crystallizes as a layered structure consisting of close-packed chloride arrangement containing layers of octahedrally coordinated In(III) centers. The motif is akin to that seen for YCl3. In contrast, GaCl3 crystallizes as dimers containing Ga2Cl6. Molten InCl3 conducts electricity, whereas AlCl3 does not as it converts to the molecular dimer, Al2Cl6.
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