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Palladium acetate

Update£º2014-11-03 16:09:49 Click£º
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Description
Product Name: Palladium acetate
Cas No.: 3375-31-3
MF: C4H6O4Pd
MW: 224.51
Description: Palladium acetate is a catalyst for many organic reactions by combining with many common classes of organic compounds such as alkenes, dienes, and alkyl, aryl, and vinyl halides to form reactive adducts. Alkenes and ¦Ð-allyl coordination to palladium(II) acetate involves sigma-type donation from the pi orbital of the alkene or ¦Ð-allyl with concomitant pi-backbonding into an empty pi* orbital on the alkene or ¦Ð-allyl. The greater the sigma donation to the metal is, the greater the pi-backbonding. The greater the pi-backbonding is, the greater the reduction in the bond order of the alkene or ¦Ð-allyl. Reduction of the alkenes or ¦Ð-allyl by coordination to palladium(II) acetate reverses the reactivity of the organic ligand allowing them to undergo reactions with nucleophiles rather than electrophiles.
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